I don't quite follow your 5% math though.
You're right about the math, I only glanced quickly at your charts, it should indeed by .05 * 916.9 * 5 = ~230gb of reserved space. (Since your graph shows numbers like 748.7gb free + 168.2gb used = 916.9gb total it's pretty safe to assume that reserved space is being counted in the 'used' section I think.)
You've got 150gb of movies, and one extra copy so that should account for another 150gb, bringing the used total to 529.25gb (300 + 230). (I'm assuming your figure of 150gb means you've got 150gb of unique files, not 75gb, let me know if this is not the case.)
Your usage total based on the graphs is 844.15 (excluding the smaller partition, since it can't have been used as a destination yet).
You're left with 844.15 - 529.25 = 314.9gb unaccounted for. 314.9/5 = 62.98gb / drive unaccounted for. The question then becomes, what is using that space?
The next step, run 'greyhole --stats' and paste the output here, that will tell us how much space is being used by the attics. If that doesn't add up you can look at the actual space used up on the pool drives for Greyhole with something like 'du -sh /var/hda/files/drives/drive2/gh'
Find those two sets of data and we'll have a clearer idea of what's going on.
Also, you can verify the percentage of space reserved on your pool volumes with the following commands (again, default is 5%):
Where /dev/sdx1 is the drive in question
sudo tune2fs -l /dev/sdx1 | grep 'Reserved block count'
sudo tune2fs -l /dev/sdx1 | grep 'Block count'
(The above assumes you have sudo setup, if not you can become root and run the commands above without sudo.)
Divide the first by the second and you'll get a percentage, probably 0.05.